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𫫇唑-4-甲醛

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𫫇唑-4-甲醛
别名 4-甲酰基𫫇唑
识别
CAS号 118994-84-6  checkY
性质
化学式 C4H3NO2
摩尔质量 97.07 g·mol−1
外观 白色固体[1]
熔点 59—61 °C(332—334 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

𫫇唑-4-甲醛是一种有机化合物,化学式为C4H3NO2。它可由噁唑-4-甲酸乙酯经二异丁基氢化铝还原制得,[2]或通过噁唑-4-甲醇经二氧化锰氧化得到。[3]它和丙基溴化镁法语Bromure de propylmagnésium反应,可以得到α-丙基噁唑-4-甲醇。[4]

参考文献

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  1. ^ 1.0 1.1 Jonathan T. Reeves, Jinhua J. Song, Zhulin Tan, Heewon Lee, Nathan K. Yee, Chris H. Senanayake. A General Synthesis of Substituted Formylpyrroles from Ketones and 4-Formyloxazole. Organic Letters. 2007-05-01, 9 (10): 1875–1878 [2022-10-05]. ISSN 1523-7060. doi:10.1021/ol070340q. (原始内容存档于2022-10-07) (英语). 
  2. ^ Ivana Šagud, Simona Božić, Željko Marinić, Marija Šindler-Kulyk. Photochemical approach to functionalized benzobicyclo[3.2.1]octene structures via fused oxazoline derivatives from 4- and 5-( o -vinylstyryl)oxazoles. Beilstein Journal of Organic Chemistry. 2014-09-18, 10: 2222–2229 [2022-10-05]. ISSN 1860-5397. doi:10.3762/bjoc.10.230. (原始内容存档于2022-10-07) (英语). 
  3. ^ Kajino, Masahiro; Hird, Nicholas William; Tarui, Naoki; Banno, Hiroshi; Kawano, Yasuhiko; Inatomi, Nobuhiro. Preparation of fused quinoline derivatives as NK2 receptor antagonists for functional gastrointestinal diseases. 2005 WO 2005105802 A1.
  4. ^ Roger J. Mulder, Cynthia M. Shafer, Doralyn S. Dalisay, Tadeusz F. Molinski. Synthesis and structure–activity relationships of bengazole A analogs. Bioorganic & Medicinal Chemistry Letters. 2009-06, 19 (11): 2928–2930 [2022-10-05]. doi:10.1016/j.bmcl.2009.04.069 (英语).